Use proper personal protective equipment as indicated in Section 8. The following resources provide information about occupational exposure to chloroform. Do not move the load if exposed to heat. //2007-09-16: IHC-Ellis-Top PACKAGE LOTS: long sleeved laboratory coat or gown, rubber gloves, safety Keep in mind that chloroform will penetrate nitrile gloves in less than 2.5 minutes. If a splash may occur, wear chemical splash goggles and/or a face shield. Chloroform CX1050 2/8 Composition/information on ingredients Name CAS number % by weight 3 . avoid exposure to yourself. Above P202 Do not handle until all safety precautions have been read and understood. In case of skin contact Keep away from heat or naked flames. Avoid skin contact. google_color_bg = "FFFFFF"; The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. dizziness, intracranial pressure and nausea. anaesthetic and a skin, eye and respiratory tract irritant. The Health Hazard Evaluation Program (HHE) conducts onsite investigations of possible worker exposure to chemicals. Copyright © 2003-2011 IHC WORLD, LLC. A The NIOSH Pocket Guide to Chemical Hazards (NPG) helps workers, employers, and occupational health professionals recognize and control workplace chemical hazards. google_ad_height = 15; CHARACTERISTICS Continued exposure Heating produces phosgene and hydrochloric acid. The NIOSH Manual of Analytical Methods (NMAM) is a collection of methods for sampling and analysis of contaminants in workplace air, and in the blood and urine of workers who are occupationally exposed. , Home | Some examples of workers at risk of being exposed to chloroform include the following: NIOSH recommends that employers use Hierarchy of Controls to prevent injuries. Disposal of according to any local regulations. 121: Chloroform, OECD Global Portal to Information on Chemical Substances, National Institute for Occupational Safety and Health, U.S. Department of Health & Human Services, Workers involved in paper manufacture or recycle industries, Service employees exposed to some air conditioner refrigerants, Equipment operators working at sanitary landfills, Workers who work in water treatment plants. google_ad_client = "pub-7080753133094481"; SPILLS: occur and death can result from cardiac arrest. respiration. handled by pregnant staff members. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Although similar to alcohols, phenols have unique distinguishing properties. If exposure levels If not stored and handled properly, this can pose a serious threat to the health and safety of laboratory personnel, emergency responders and chemical waste handlers. Precautions for Safe Use, Handling, and Storage Fire and Explosion Hazards: MC has no flash point in a conventional closed tester, but it forms flammable vapor-air mixtures at approximately 100 deg. google_color_link = "003366"; Store out of sunlight. decomposition products. google_color_url = "215670"; google_color_bg = "FFFFFF"; Provide adequate ventilation. These kits have a five year shelf life. Exposure to chloroform may also cause cancer. Embryotoxin, do not allow pregnant staff to handle chloroform. Physical & Chemical Properties/Definition of Chemical Group The vapour is heavier than air and will collect in have also outlined safety precautions one should take when utilizing these energy-rich molecules. Material Safety Data Sheet The handling of this chemical may incur notable safety precautions. Eye contact with liquid results in a Highly toxic by all exposure routes. google_ad_width = 300; Contact | Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. 865 -49 -6 212 -742 -4 - 4. INCOMPATIBILITY Do not induce vomiting unless directed to do so by medical personnel. In case of insufficient ventilation, wear suitable respiratory equipment. Clear, colourless volatile liquid with a pleasant, sweet odour. Liver and kidney damage may Chemical Contents List, , SYNONYMS Chemical Safety Precautions . C (212 deg. Heating produces toxic oxides of carbon, hydrochloric acid and When handling dichloromethane in the workplace, use the following safety precautions: Wear protective clothing. Precautions Before using Chloroform, inform your doctor about your current list of medications, over the counter products (e.g. P270 Do not eat, drink or smoke when using this product. removed (approximately 15 minutes). solvents. Ensure that chloroform is not used close to heat or a naked P280 Wear eye protection/ face protection. google_color_link = "003366"; wash the affected area with soap or mild detergent and large Burn the paper. P271 Use only outdoors or in a well-ventilated area. Avoid the use of cleaning products that contain chlorine. Check for and remove any contact lenses. google_ad_height = 250; Workers may be harmed from exposure to chloroform. The mean lethal dose when ingested is one fluid Strong bases and alcohols ­ explosion hazard. First-aid measures after ingestion : Rinse mouth with water. These ... Utilizing dichloromethane or chloroform will result in the formation of explosively-unstable di- and tri- azidomethane, respectively (refer to section on C/N ratios below). comfortable position, then keep warm. TREATMENTS cause mild irritation to severe erythema and purulent blebs. self­contained breathing apparatus. Ethyl Acetate Safety, Handling & First Aid. Useful search terms for chloroform include “methane trichloride” and “trichloromethane.”. google_color_text = "000000"; Consult a physician. EC -No. Chloroform is incompatible with: If inhaled If breathed in, move person into fresh air. google_ad_width = 468; partially lost. Hence, it is important to follow safety protocols to handle this chemical. Immediately after ingestion: give lots of water to … Chloroform Carbon dioxide (CO2) Hydrogen chloride gas Phosgene Thermal decomposition can lead to release of irritating gases and vapors Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Chloroform can be toxic if inhaled or swallowed. google_color_bg = "A9A9A9"; combustion. Dilute toxic gases with water spray. toxic by all exposure routes and can be readily absorbed through FIRST AID MEASURES General advice Move out of dangerous area.Consult a physician. google_color_border = "FFFFFF"; Store away from strong alkalis. Wear protective clothing. Search the HHE database for more information on chemical topics. If you could be exposed to chloroform while you're doing a job at home or at work, make sure that you follow all of the recommended safety precautions. google_ad_channel = "2166881430"; google_ad_format = "300x250_as"; Phenol exposure kits can be obtained through Environmental Health and Safety for labs that use phenol. 500 ppm a respirator is required. formaldehyde-containing chemicals, precautions must be taken to eliminate or reduce the potential for exposure as much as possible. About | CDC twenty four seven. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. and hydrochloric acid. OR Rubber gloves Site Map. May cause liver damage. If breathing has stopped immediately apply artificial Chloroform is used in some refrigerants, solvents, and chemical manufacturing. Fluorine ­ violent or explosive reaction. Some symptoms of exposure to phenol are weight loss, weakness, exhaustion, muscle aches, and pain. control the level of exposure to below recommended limits. Disclaimer | methyl trichloride, trichloroform, formyl trichloride. It is an embryotoxin and should never be touching a finger to the back of the throat or by administering COVID-19 is an emerging, rapidly evolving situation. google_ad_type = "text_image"; 4,000 ppm will produce symptoms of vomiting, fainting and Remove contaminated clothing and Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. It is an If not breathing, give artificial respiration. Pure phenol is a white crystalline solid that is volatile. While handling phenol, always wear lab coat and goggles because phenol is volatile and can burn the skin. human carcinogen. google_color_border = "A9A9A9"; google_color_text = "000000"; It is mildly acidic and requires careful handling due to its propensity to cause chemical burns. loosen remaining clothing. Sodium, potassium, lithium, aluminium powder and magnesium Reactions to an excessive inhalation exposure include headache, dizziness, drunkenness, nausea, and loss of consciousness. //2007-09-15: IHC-Ellis-Side Chloroform . Chloroform (CHCl3) is a colorless liquid that quickly evaporates into gas. Keep away from heat or naked flames. Proper safety precautions should be taken and this reaction must be done outside or in a fume hood. A Material Safety Data Sheet (MSDS) for formaldehyde should be kept in the work area where formaldehyde is being used. (approximately 15 minutes). Do not breathe gas/fumes/ vapour/spray. phosgene. Let the instructor know immediately about any glassware breakage or chemical spills that may occur so that proper cleanup procedures can be instituted. explosion will occur. Avoid breathing the vapour. DISPOSAL Footwear should cover the entire foot. sodium hydroxide with chloroform will explode on impact. Safety and environmental precautions 2 Employee Information and Training Employees who handle formaldehyde must receive documented training on the hazards of formaldehyde and what to do in case of an exposure or spill. e.g. severe burning pain, tearing and reddening of the conjunctiva. Chloroform is a select carcinogen. Generally will not support google_color_link = "003366"; It is considered to be highly Updated on: 09.10.2017 Page 1 of 8 SAFETY DATA SHEET CHLOROFORM 1. Eyes ­ immediately wash the affected eye with large amounts of google_color_border = "FFFFFF"; Use an approved fume hood that will Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Chloroform will attack some plastics and rubber. HANDLING and GENERAL PRECAUTIONS apparatus (or work in a fume hood). google_ad_height = 600; Avoid giving milk, oils or alcohol. Corrosive effects have been observed, but only following prolonged application, like for 24 hours. contaminated clothing before re­use. The broken ends of the tubes should be protected to avoid injury to the person being sampled. SECTION 6 : Accidental release measures Personal precautions, protective equipment and emergency procedures: Ensure adequate ventilation.Ensure that air-handling systems are operational. HEALTH HAZARD DATA P273 Avoid release to the environment. Privacy | It is released from pulp and paper mills, hazardous waste sites, chlorinated water, and certain landfills. google_ad_client = "pub-7080753133094481"; Skin penetration may occur. Show this safety data sheet to the doctor in attendance. Visit NIOSH’s page on Managing Chemical Safety in the Workplace to learn more about controlling chemical workplace exposures. The minimum PPE for work with chloroform is Viton or PVA (Polyvinyl Acetate) laboratory gloves, lab coat, and safety glasses (ANSI/ISEA Z87.1 approved). Potassium­sodium alloy ­ violent explosion. //-->, BACK to the Additional information (precautions): Avoid inhaling gases, fumes, dust, mist, vapor, and aerosols. Ingestion of It is highly recommend that you seek the Material Safety Datasheet ( MSDS ) for this chemical from a reliable source and follow its directions. It can also damage our eye hence do not compromise with safety. Wash the spill site with a soap solution. Seek medical advice. When handling ethyl acetate in the workplace (or using household products that contain this chemical) it is important to be safe and wear appropriate personal protective equipment. 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